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  • Molecular sab cib hauv cov lus qhia

Molecular sab cib hauv cov lus qhia

Kev piav txog

Cov molecules ntawm cov tshuaj sib txawv yog qhov txawv ntawm qhov tseem ceeb thiab qhov loj ntawm kev kos duab, yog li cov duab hu ua "molecular sab cib".

Molecular sab cib (tseem hu ua hluavtaws Zeolite) yog silicated microporousrystal. Nws yog cov pob txha pob txha uas yooj yim muaj cov khoom sib xyaw ua ke ntawm silicon aluminate, nrog rau cov hlau xaim (k +, thiab lwm yam) kom sib npaug cov kev tsis zoo ntawm cov siv lead ua. Hom molecular feem ntau muab faib ua ib hom, x hom thiab y ntaus raws li nws cov qauv siv lead ua.

Tshuaj mis ntawm Zeolite Hlwb:

Mx / n [(alo.2) x (sio.2) Y] wh.2O.

MX / N :.

Cation ion, khaws cov lead ua kom nruab nrab nruab nrab

(ALO2) X (Sio2) Y:

Lub cev pob txha ntawm cov Zeolite muaju, nrog cov duab sib txawv ntawm qhov thiab raws

H2O:

Lub cev muaj kab mob lub cev tau kos duab

Nta:

Ntau yam adsorption thiab kev cawm dim yuav ua tau
Ntaus cov molecular sab cib

Lub ntsiab tivthaiv ntawm hom molecular sab nrov yog silicon aluminate.

Lub ntsiab crystal lub qhov yog lub psosaring.the aperture ntawm lub crystal aperture yog 4å (1Å
Txauv ntawm CA2 + rau NA + nyob rau hauv 4a molecular sab cib, sib sau ib aperture ntawm 5A, uas namely calcium a) ib leeg (aka calcium sieve;
K + rau ib qho kev sib dhos, ua ib qho aperture ntawm 3A, uas yog ib tug 3a (Oka Potassium a) cov roj ntsha sab.

 

Hom X molecular sab cib

Lub ntsiab tivthaiv ntawm X molecular sab sib luag yog silicon aluminate, lub ntsiab crystal lub qhov yog kaum ob lub nplhaib qauv qauv.
Txawv crystal qauv tsim cov molecular sileveryryry, kuj hu ua 13x (kuj hu ua Sodium x hom) molecular sieve;

CA2 + Pauv rau NA + nyob rau hauv ib tug 13x molecular sieve, sib sau ib tug molecular sieveryryry, kuj yog paub li calcium x) molecular sab cib.

 

Ntaus cov molecular sab cib

Molecular siry1

Hom X molecular sab cib

Molecular Siary2

Daim ntawv thov

Cov adsorption ntawm cov khoom siv los ntawm kev kos npe rau lub cev (vander WATORS yuam), nrog lub qhov muaj zog polarbation thiab courtal molecules (xws li dej) thiab unsaturated molecules.

Lub aperture faib ntawm cov suab paj nruag molecular yog cov khoom siv tsis zoo, thiab tsuas yog cov tshuaj nrog cov kab sib chaws me me dua lub qhov taub uas hla hauv lub qhov sab hauv ntawm cov nplais molecular.


Xa koj cov lus rau peb: